Adsorption of Gases on Heterogeneous Surfaces

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Academic Press, Dec 2, 2012 - Technology & Engineering - 624 pages
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All real solid surfaces are heterogeneous to a greater or lesser extent and this book provides a broad yet detailed survey of the present state of gas adsorption. Coverage is comprehensive and extends from basic principles to computer simulation of adsorption. Underlying concepts are clarified and the strengths and weaknesses of the various methods described are discussed.

  • Adsorption isotherm equations for various types of heterogeneous solid surfaces
  • Methods of determining the nature of surface heterogeneity and porosity from experimental data
  • Studies of phase behavior of gases absorbed on heterogeneous solid surfaces
  • Computer simulation of adsorption on heterogeneous solid surfaces
 

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Contents

Chapter 1 Basic Principles
1
Chapter 2 The Empirical Adsorption Isotherms
35
Chapter 3 Calorimetric Effects in Adsorption
59
Chapter 4 The Interpretation of Empirical Isotherms in Terms of Surface Heterogeneity
83
Chapter 5 Ideal Monolayer Adsorption on Heterogeneous Surfaces
112
Chapter 6 On the Nature of the Heterogeneity of Real Solid Surfaces
138
Chapter 7 Lowpressure Adsorption and the Virial Description
199
Chapter 8 Mobile Monolayer Adsorption with Lateral Interactions
238
Chapter 10 Multilayer Adsorption on Heterogeneous Surfaces
351
Chapter 11 Numerical Methods of Evaluating the Adsorption Energy Distribution
420
Chapter 12 Multisite Occupancy Adsorption on Heterogeneous Solid Surfaces
491
Chapter 13 Computer Simulation of Adsorption on Heterogeneous Solid Surfaces
529
Author Index
553
Subject Index
564
Index of Systems
574
Copyright

Chapter 9 Localised Monolayer Adsorption with Interactions between Adsorbed Molecules
288

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