Barrier polymers and structures
American Chemical Society, 1990 - Technology & Engineering - 406 pages
This volume provides a comprehensive treatment of the state of science and technology in the area of barrier polymers and barrier structures. Among the topics covered in its 20 chapters are structure-property relationships of Saran materials and nylons; approaches to engineering around the sensitivity of barrier polymers to humidity; characterization of sorption kinetics in several glassy polymers for a broad spectrum of penetrants; complex barrier structures; and flavor scalping. It presents fundamental principles along with complementing discussions of applications of these principles.
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Fundamentals of Gas Diffusion in Rubbery and Glassy
Effects of Structural Order on Barrier Properties
Transport of Plasticizing Penetrants in Glassy Polymers
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activation energy American Chemical Society amorphous aromatic aseptic barrier layer Barrier Polymers barrier properties barrier resins bisphenol blow molding bromobenzene calculated carbon Chem chloride concentration containers copolymer correlation crystal crystalline curves d-limonene Datyner decrease density desiccant diffusion coefficient dual-mode sorption effect Equation ester EvOH layer experimental film flavor compounds fluorinated food packaging free volume function gas transport gases glass transition glassy polymers HDPE heat Henry's law Hopfenberg humidity increase interactions kinetics Koros LDPE liquid materials measured mechanical membrane molecular monomer multilayer nylon orientation oxygen barrier oxygen permeability packing parameters penetrant molecules permeation rate Phys plasticization platelets polyamide polycarbonate polyethylene polypropylene pressure PVDC ratio reduced retort rubbery samples segments SELAR semicrystalline semicrystalline polymers shown in Figure solubility coefficient solvent sorption isotherm storage sulfonation sulfur trioxide Table temperature thickness toluene transport properties untreated values vapor Vrentas water activity