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Chapter ONE Introduction 1
11 other sections not shown
acceptor activated complex activation energy adiabatic angle angular distribution applied approximation assumed atom barrier calculation Chem chemical classical coefficient collision energy collision process configuration consider curve cyclobutane decomposition degrees of freedom density determined diatomic differential cross section diffusion discussed donor effect elastic scattering electronic energy transfer equation equilibrium evaluated excited experimental expression Eyring frequency given by eq Herschbach impact parameter inelastic integral interaction kcal/mole kinetic Laplace transformation mechanism method of steepest molecules motion obtained orbitals oscillator particles partition function perturbation phonon Phys potential energy surface quantum radiationless transitions rate constant reactants reaction coordinate reaction cross section reaction rate represents repulsive rotational RRKM saddle point solution solvent steady-state approximation steepest descent Substituting eq symmetry temperature term theoretical theory thermal tion total cross section trajectory transition probability translational energy unimolecular reactions velocity vibrational relaxation vibronic wave function yields