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Entropy and equilibrium
Equilibrium in chemical systems
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activity coefficient atm pressure atoms behaviour benzene boiling point Calculate chemical potential chemical reactions chemical thermodynamics components concentration consider constant pressure defined determine dilute solutions dissociation dwrev energy levels enthalpies of formation entropy change equation equilibrium constant example expansion expressed follows Raoult's Law free-energy change freezing point gases Gibbs free energy heat capacity Henry's Law hydrogen ideal solution illustrated in Fig internal energy ions kJ mol kJ mol"1 liquid measure mechanical system microstates molality molar mole fraction mole of gas mole of reaction molecular mass n-butane naphthalene negative number of molecules number of moles obtain partial pressure partition function perfect gas phase position of equilibrium Raoult's Law reactants relation reversible change rotational RTln Section 4.4 solid solubility solvent standard electrode potential system at constant thermodynamic properties thermodynamic quantities vapour pressure vibrational zero