What people are saying - Write a review
We haven't found any reviews in the usual places.
Theory of Unimolecular Reactions
Atomic and FreeRadical Processes
Reactions in Solution
5 other sections not shown
Other editions - View all
absorbed absorption acetaldehyde acid activated complex activation energy Arrhenius equation atoms Calculate the rate catalyst chain reaction chem Chemical Kinetics chemical reaction coefﬁcient collision theory deactivation decomposed decomposition decrease determined difﬁcult dissociation electrons energised molecules entropy entropy of activation enzyme example experimental fast reactions Figure ﬂame ﬂow free radicals frequency factor gas-phase reactions given gives graph half-life hydrogen hydrolysis initial concentration iodide iodine ionic strength ions isomerisation kJ mol'1 linear with slope low pressures measured method mol dm'3 molecular molecules nitrogen occur oxygen photochemical photolysis plot of loglo polymerisation quantum yield radiation rate constant rate equation rate of reaction reactant reactant molecules reaction is ﬁrst reaction is second reaction rate second order second-order shown in ﬁgure slope equal solvent steady-state steady-state approximation studied techniques temperature thermal thermodynamic Time/min tube unimolecular unimolecular reactions volume wavelength