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Acad Acta activity adduct agent aldehyde alkyl amine oxidase anion aromatic autoxidation binding Biochem Biochemistry Biol bioluminescence Biophys bond Bruice carbon monoxide carbonyl catalase catalyzed catechol cation chelate Chem chemical chemistry cleavage compounds copper cytochrome P450 decomposition derivatives detected dioxetane dioxygenase diradical electron enzymatic enzyme epoxide fatty acid ferric ferrous Figure flavin flavin monooxygenases formation Fridovich ground-state dioxygen Hayaishi heme hemerythrin hemoglobin high-spin hydrogen peroxide hydroperoxide hydroxy hydroxyl radical hydroxylase imidazole inhibitors intermediate iron kinetic Lett ligand lipid lipoxygenase low-spin Massey mechanism metal microsomes molecular oxygen molecule Natl nucleophilic olefins one-electron orbital oxidation oxygen oxygen atoms oxygenase pathway perepoxide peroxidase Photobiol Photochem porphyrin Proc prostaglandin endoperoxide protein proton quenching react reaction of singlet reaction of superoxide reactive reduced resonance result singlet dioxygen solution solvent species spectra spin structure studies substrate superoxide dismutase superoxide ion triplet dioxygen U.SA