Biocide guanidine containing polymers
This volume deals with chemistry of polyelectrolytes, namely biocide guanidine containing polymers, discussing both synthesis of new guanidine containing monomers of diallyl and acrylic nature and their structure and investigation of their radical (co)polymerization and properties of new (co)polymers. The first parts of the book describe radical polymerization of these monomers and their co-polymerization with diallyldialkylammonium derivatives, features of their kinetic behavior in these processes (for example, polymerization rates, reactivity ratios) The sections on phycal chemical methods (IR, NMR, DSC etc.) are especially important for studying of structure and properties of synthesized monomer and polymer compounds. The book is finely illustrated with about hundred original figures, schemes and tables including kinetics, NMR, IR spectroscopy, biocide and other data.
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Synthesis of dially 1 guanidine containing i
RADICAL COPOLYMERIZATION OF GUANIDINE
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1H NMR spectra A.I. Martynenko A.M. Esmurziev AA and MAA acrylic acids AIBN analogous bacterial bands biocide cell chain propagation characteristic Chem chemical shifts comonomer comparison compounds conformational constants conversion degrees copolymerization copolymers corresponding counter-ion D.A. Topchiev DADMAC DADMAC units DADMAC-GA dependence diallyl diamagnetic diamagnetic shift dis-screening Elemental analysis results experiments Figure formation G.E. Zaikov guanidine groups homopolymers hydrogen bonding hydrophobic interactions increase influence initial intensive band investigations ion force ion pairs ionized kinetic low-molecular MAA polymerization macromolecules membrane methacrylate methacrylate-anion methacrylic acid methanol mole l"1 molecular mass molecules monomer monomer concentration monomer salts N.A. Sivov observed order by monomer PAG and PMAG PMAA polyelectrolytes polymer polymerization in water polymerization process polymerization rate presented protons radical polymerization reaction solution revealed rise of pH Russian Scheme signals of protons solvents spectrum stability structure synthesis Table tion V.A. Kabanov values viscosity Vysokomol water mediums water solutions