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absorption line actual applied magnetic field associated axis biochemical molecules biological bonding carbon carcinogenic cavity cavity resonator complex components compounds concentration copper atoms corresponding crystal detector detailed detected direction effect electric field electron resonance electron resonance absorption electron resonance spectra electron resonance spectrometer electron resonance studies electron spin electron spin resonance ENDOR energy levels enzyme equation fact free radicals g-value gauss haem normal haem plane haemoglobin hence hydrogen hyperfine pattern hyperfine splitting hyperfine structure illustrated in Fig indicated interaction iron atom kc/s kinetics klystron large number ligand atoms line-width magnetic field magnitude mechanism metal ions microwave microwave frequency microwave power modulation molecular orbital myoglobin nitrogen noise nucleus observed obtained orientation parameter particular possible produced protein protons quantum number radiation reaction saturation seen shown in Fig single crystals solution specimen spectrometer spectrometer system spin-label structure superhyperfine symmetry temperature tion transition group atoms unpaired electron value variation wavelength xanthine oxidase