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1,4-benzoquinone 6-hydroxydopamine 7-hydroxychlorpromazine acetonitrile adsorbed adsorption aqueous ascorbic acid base-off base-on behavior biological buffer carbon paste electrode catalytic catecholamines cation radical Chem chemical chlorpromazine co-workers cobalamins coenzyme compound concentration controlled-potential corresponding coulometry curve cyanide cyanocob(lll)alamin cyclic voltammetry cyclic voltammogram cytochrome decrease dimethylformamide dopamine Eggins elec electrochemical oxidation electrochemical reduction electrochemistry electrode reaction electrolysis electron transfer electron-transfer electrooxidation enzymatic enzyme ferredoxin give half-wave potential heme hydrogen hydroquinone intermediate L-ascorbic Lexa mechanism mercury electrode molecule Neptune and McCreery o-quinone observed occurs one-electron oxidase oxidation wave p-benzohydroquinone peak current peak potential perchlorate permission phenothiazine phosphate platinum electrode polarographic polarographic reduction wave proposed protein proton quinone R. N. Adams radical anion rate constant redox potential Reprinted shown in Eq shown in Fig solution structure studies Supporting electrolyte surface Table thin-layer tion two-electron ubiquinone ubiquinone-50 uric acid vitamin B12 voltammetric voltammetric oxidation peak