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Spectral Changes Produced
EXPERIMENTAL TECHNIQUES AND RESULTS
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absorbancy units absorption activation energy added addition adsorption amount analysis aqueous layer argon assumption average bond rupture BrBr caging calculated cell Chromatographic column compounds counting jacket counting rate cryostat curve d(HI dark exchange decay determined dewar effect electron paramagnetic resonance equation ethane ethyl iodide glass ethylene experimental experiments explanation fraction frozen G-value gamma rays Gas Chromatographic ground joint Hamill and Young Hanrahan hydrocarbon indicates iodine production irradiation isomeric transition kcal./mole light liquid air liquid ethyl iodide liquid nitrogen maximum melted molecule moles normal rate observed obtained organic layer peaks Photochemical Exchange photolysis of ethyl photolysis of liquid photolytic pressures Pyrex quantum yield quartz quartz tube radiolysis rate of iodine rate of production ratio HI/I reaction 2a reported room temperature runs scavenger sealed separation solution spectrophotometric spectrum stopcock studied Table thermal ethyl radicals trapped umoles/hr units per hour vacuum line vycor Willard