Catalysis in Chemistry and Enzymology

Front Cover
Courier Corporation, 1987 - Science - 836 pages
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Exceptionally clear, carefully written treatment of the nature of catalysis of reactions in aqueous solution. Coverage of mechanisms for catalysis, forces in aqueous solution, carbonyl- and acyl-group reactions, practical kinetics, and much more. Extensive bibliography. "... a masterpiece."—Nature.
 

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language is tougher and not east to nderstand and their are a lot of contradictions.

Contents

The Appendix has its own table of contents see pp 615616
1
Approximation 7
7
Chapter
9
Chapter 3
27
Chapter 10
59
Chapter 6
81
General AcidBase Catalysis
163
The Brønsted Relationship
178
DonorAcceptor and Charge Transfer Interactions
437
Related Phenomena and Long Electrondeficient Bonds
449
Charge Transfer and DonorAcceptor Interactions in Biochemistry
459
Tetrahedral intermediates and the ratedetermining step
467
Change in ratedetermining step with changing concentra
474
Change in ratedetermining step with changing structure
480
Partitioning of an intermediate after the ratedetermining
487
DoO and HC3
501

Isotope Effects
243
Equilibria in Water and Deuterium Oxide
250
Steric effects
257
Nonlinear transition states
263
Some Elementary Conclusions Regarding Deuterium Isotope
273
Isotope effects on the Michaelis constant
279
Manifestation of Enzymatic Specificity in Maximum Welocities
288
FORCES IN AQUEOUs solution
321
Electrostatic Interactions
351
Concentrated salt solutions
358
Explanations
364
Concentrated salt solutions
375
Hydrophobic Forces
393
rºom and HOR
508
RCSR and HOR
517
RCSR and H N R
537
Practical Kinetics
555
The endpoint
561
The Utilization of Pseudo Firstorder Rate Constants
568
Effect of pH and ionization of the reactants
577
Salt and solvent effects
585
teadystate Rate Equations
597
Thermodynamic activation parameters
605
Summary of rules for intepretation
612
Name Inder
823
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