## Centrifugal Distortion of Axial Molecules and The Potential Functions of the Methyl Halides |

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ammonia-like molecules angular momentum approximation atomic weight axial molecules axially symmetrical molecules axis of symmetry BAND CALCULATED OBSERVED BrCH3 bromine center of gravity centrifugal distortion centrifugal force stretching Chem coefficients coordinates X1 correspond cubic equation D. M. Dennison determined diagonal dimensions displacements distance dynes/cm equilibrium positions evaluated expression FCH3 FINAL CALC force constants fundamental frequencies H angle H C H H. H. Voge halogen atom hydrogen atoms ICH3 infra-red spectrum kinetic and potential matrices methane methyl group methyl halides moments and products moments of inertia motions normal frequencies normalized first minors observed frequencies observed values obtain order of approximation paper parabola parallel frequencies perpendicular bands perpendicular frequencies Phys plane ponents potential energy function potential function products of inertia pure rotation lines respectively selection rules structure spacing Table three X atoms tion values of k4 vibrational waves per cm WJKJK Wright and Randall ZYX3 molecule