## Chemical Thermodynamics |

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### Contents

1 | 8 |

1 | 17 |

Multicomponent systems 3 1 Thermodynamics of multicomponent systems 3 1 1 The fundamental equation of thermodynamics 3 1 2 Phase equilibri... | 22 |

Chemical Thermodynamics 7 | 25 |

17 | 45 |

Nonideal solutions 6 1 Deviations from Raoults law and the activity coefficient 6 2 Modified Raoults law 6 3 Empirical activity coefficient models 6 ... | 47 |

20 | 54 |

The next step | 68 |

Equations of state 10 1 The principle of corresponding states 10 2 The van der Waals equation and cubic equations of state 10 3 Equations of state fo... | 70 |

We have 100s of comprehensive | 73 |

www ubs comgraduates Looking for a career where your ideas could really make a difference? UBSs | 80 |

### Common terms and phrases

activity coefficient activity coefficient models azeotropic azeotropic composition azeotropic systems binary mixture bookboon.com Figure bubble point bubble point curve carbon dioxide chemical potential coexisting liquid phases composition x2 critical temperature Data taken derive deviations from Raoult’s dew point curve diagram for mixtures Download free ebooks ebooks at bookboon.com enthalpy equal equation of thermodynamics extensive property ﬁnd fluids fraction of component freezing curve Gibbs free energy Gibbs phase rule Gibbs-Duhem equation Helmholtz free energy Henry’s law ideal gas ideal solution model line in Fig methane and ethane modified Raoult’s law molar Gibbs free molar volume mole fraction mole numbers molecules non-ideal number of moles parameter partial molar properties partial pressure phase behavior phase diagram phase separate pure component pure methane pure species pvap2(T RT lnx solid line system temperature tangent line temperature and pressure total number Txy diagram vapor phase vapor pressure curve variation Waals equation γα μα