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Complex equilibria and equilibrium constants
General characterization of complex equilibrium systems
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acid Acta Chem activity coefficients anionic application aqueous solution Bjerrum calculated chemical chemical shift Chim complex equilibria complex MeL components concentration ratios considerations Coord coordination sphere copper(II correlations corresponding Dalton determination dissociation distribution quotient dlog donor atoms donor groups effect electrode electrolyte enthalpy equation equilibrium chemistry equilibrium concentration equilibrium constants equilibrium processes equilibrium studies equilibrium systems ethylenediamine evaluation example experimental data extraction formation constants formation curve formed function glycine hydrolysis Inorg interaction ionic strength ligand concentration logarithm measurements MeL2 MeLH metal complexes metal ion concentration method microconstants mixed ligand complexes mole fraction mole ratio molecules Nagypal nickel(II Nucl obtained outer sphere complexes partial mole fraction pH-metric photometric Phys polynuclear complexes protonation protonation constants reaction Reproduced with permission Rossotti Scand Sillen solubility solvation solvent species stepwise complex formation stoichiometric structure Talanta titration titration curve total concentrations two-component values various