Chemistry of Interfaces |
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A+ B A+ acid adsorbed adsorbed atom adsorbed film adsorbed layer adsorption adsorption isotherm adsorption potential argon assumed behaviour benzene bulk phase calculated capillary Chem chemical potential chemisorption Colloid component concentration considered constant contact angle crystal curve density dipole dislocation dispersion forces distance dividing surface double layer drop effect enthalpy equilibrium ethanol example experimental Faraday free energy function heat of immersion hydrocarbon illustrated in Fig increases interaction interfacial tension interphase involved ionic ions Jaycock krypton Langmuir lattice localised London measured meniscus metal method microtome mmol mN m¹ molecular moles monolayer n₁ N₂ oxide Phys plane potential energy pressure region relaxation rutile Schottky defects shown in Fig sodium chloride solid surface solution surface area surface energy surface excess surface tension Table temperature thermodynamic usually values vapour viscosity volume wetting