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IDEAL IMPERFECT AND DEFECT CRYSTALLINE
ELEMENTS OF THE THEORY OF THE DEFECT
OUTLINE OF EXPERIMENTAL APPROACH
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absorption absorption spectrum activation energy adsorbed adsorbed atoms adsorption Ag2S alloys anion lattice atoms or ions behaviour catalytic processes cation vacancy chemical chemisorbed chemistry conduction band Cu2O deduced defect aggregates defect concentration defect solid diffusion Disc Faraday Soc discussed disorder electronic conductivity electronic energy energy band energy levels equilibrium concentrations example excess excitation F-centre Figure films Frenkel Frenkel defects halide heterogeneous catalysis hydrogen impurity atom insulator interaction interface interstitial atoms ionic conductivity ionic solids isotherm kind layer low temperatures mechanism methods migration molecules n-type optical oxide oxygen partition function perfect crystal phase boundary photoconductivity positive hole possible potential energy problem properties quantum reactant Schottky defects semi-conductor solid solution statistical mechanics stitial stoicheiometric composition stoicheiometric crystal stoicheiometric defect structure substitutional impurity surface symbol symmetry tarnish reactions thermal Ti2+ tion transition types of defect vacant lattice valence band Wagner zinc