Chiral Sulfur Reagents: Applications in Asymmetric and Stereoselective Synthesis
Over the last three decades, more than 40 different classes of chiral (mirror-image) sulfur compounds have been described, and a number of useful procedures and applications have been developed for their use. Emphasizing modern methodologies, Chiral Sulfur Reagents demonstrates the great potential of enantionmerically pure sulfur reagents in transmitting chirality to other centers. Each chapter highlights the synthesis and synthetic uses of a particular class of chiral sulfur reagent, followed by examples of the most important experimental procedures.
What people are saying - Write a review
We haven't found any reviews in the usual places.
Chiral Sulfinic Acid Derivatives
References 3 2
References 3 3
References 3 4
References 3 5
References 3 6
a-phosphoryl sulfoxides a-sulfinyl carbanions acetone acid added dropwise adducts alcohol aldehydes alkyl allyl sulfoxides anion aryl asymmetric induction asymmetric synthesis carbanion carbon carbonyl chelate Chem chiral sulfur Cinquini conjugate addition corresponding cyclic derivatives diastereomeric diastereomerically pure diastereoselectivity diethyl Drabowicz dried electrophiles enantiomer enantiomerically pure Equation equiv ether evaporated extracted give Grignard reagents hexane i-Pr ketones lithium MeOH methyl MgSO4 Mikolajczyk mmol moiety N-alkylidenesulfinamides n-Bu n-BuLi n-butyllithium n-Pr nucleophilic obtained optically active organic layer p-toluenesulfinate p-tolyl sulfoxide Perkin Trans Ph Ph prepared procedure purity racemic ratio reaction mixture rearrangement recrystallization room temperature saturated Scheme silica gel sodium Solladie solution solvent stereochemical stereoselectivity stirred substituents substrates sulfilimines sulfinamides sulfinates sulfinic esters sulfinyl chlorides sulfonium salts sulfoximines sulfur sulfur atom sulfur compounds Synthesis of Chiral synthesis of optically t-Bu Table Tetrahedron Lett Tol-p vinyl sulfoxides yield ylide