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Thermodynamic Properties of Fluids
Systems of Variable Composition
Behavior of Real Fluids
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acentric factor activity coefficients application of Eq azeotrope becomes behavior binary solution binary system calculation chemical potential composition dependence const constant-composition cubic equation curve data reduction defined definition density derivatives determined diagram differential enthalpy entropy equilibrium evaluated Example experimental Figure fugacity coefficient Gibbs function Gibbs-Duhem equation given by Eq gives Henry's constant Henry's law ideal solution ideal-gas integration isothermal Lewis-Randall rule liquid phase Margules equation mixing rules mixture molar volume mole fractions mole numbers parameters partial molar property partial properties phase equilibrium phase rule plot procedure property changes pure fluids pure liquid pure species PVT system quantities Raoult's law Redlich-Kwong equation reduced relation represented residuals result RT2 RT saturation solubility solvent temperature and pressure tion values vapor phase vapor pressures vapor/liquid versus virial coefficients virial equation VLE data yields zero