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Calculation of solution equilibria
Uncertainty of results
Summary of conclusions
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ACPr adiabatic expansion alkali chloride hydrothermal aqueous solutions cal/mole deg calculated from Eqn cation Chem co-ordinated water complex formation composition considerable decrease degrees of formation Delta approximation dissociation constants electrolyte solutions elevated temperatures enthalpy enthalpy of association entropy of association equations equilibrium constants error evaluation experimental solubility fluid inclusions galena solubility geochemical geothermal gradient heat capacity hydration hydro hydronium hydrothermal equilibria hydrothermal ore deposits hydrothermal rock alteration individual ion activity involved ion activity coefficients ionic irreversible adiabatic expansion isentropes isosolubility curves kcal/mole lead chloride lead chloride complexes ligand low temperatures metal ion molal multicomponent NaCl numbers indicate ore-forming metals parameters Pb++ PbCl PbCl+ PbCl2 PbCl4 polysulfide precipitation ratios reaction relatively slopes sodium chloride sodium chloride solutions solid phases solubility of galena solutions at elevated species in solution sphalerite standard entropy temperature variation temperatures and pressures thermochemical thermodynamic thermodynamic data uncertainty values of log water molecules