Electrochemical SystemsThe new edition of the cornerstone text on electrochemistry Spans all the areas of electrochemistry, from the basics of thermodynamics and electrode kinetics to transport phenomena in electrolytes, metals, and semiconductors. Newly updated and expanded, the Third Edition covers important new treatments, ideas, and technologies while also increasing the book's accessibility for readers in related fields.

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Contents
INTRODUCTION  1 
PART A THERMODYNAMICS  27 
TRANSPORT PROCESSES  47 
THE ELECTRIC POTENTIAL  85 
ACTIVITY COEFFICIENTS  99 
REFERENCE ELECTRODES  131 
POTENTIALS OF CELLS WITH JUNCTIONS  149 
PART B ELECTRODE KINETICS AND OTHER  169 
TRANSPORT PROPERTIES  335 
FLUID MECHANICS  347 
CURRENT DISTRIBUTION AND MASS  369 
CONVECTIVETRANSPORT PROBLEMS  377 
APPLICATIONS OF POTENTIAL THEORY  419 
EFFECT OF MIGRATION ON LIMITING CURRENTS  459 
CONCENTRATION OVERPOTENTIAL  491 
CURRENTS BELOW THE LIMITING CURRENT  500 
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Common terms and phrases
activity coefficients adsorbed anode applied approximation binary electrolyte boundary conditions calculated calomel electrode cathode cell potential Chapter charge density chemical potential chloride composition concentration profiles conductivity constant convection current density current distribution Debye Debye length depends diffuse layer diffusion coefficient dilute solutions dimensionless double layer effect electric field electrochemical potential Electrochemical Society electrochemical systems Electrochemistry electrode potential electrode reaction electrode surface electrolyte electrolytic solution electrostatic equilibrium exchange current density expression Figure flow fluid flux density hydrogen electrode interaction interface involved John Newman Laplace's equation limiting current liquid junction liquidjunction potentials mass transfer measured mercury metal migration mol/kg molality molar number of species obtain ohmic potential drop oxide oxygen parameter phase porous electrode potential difference pressure problem reactant reference electrode relative rotating disk secondary reference Section semiconductor shows solubility solvent standard cell potential standard electrode potentials supporting electrolyte surface overpotential temperature thermodynamic transference number variation velocity zero