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A Simple Approach to Crystal Field Theory
Calculation of Magnetic Properties of the Ground State
Improvements to the Simple Crystal Field Theory
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angular momentum anisotropic approximation assume atomic axes axis bleaney CaF2 calculate cavity Ce3+ Chapter Co2+ components configuration consider cos2 covalent Cr3+ crystal field crystal field theory cubic field cubic symmetry degeneracy dependence detector diagonal diagonalise direct process doublet effective spin eigenvalues energy levels Equation example experimental Fe3+ field H field splitting free ion frequency functions g-factor g-values Gc/s ground groundstate group ions hyperfine splitting hyperfine structure illustrate interaction iron group isotropic klystron Kramers doublet lattice ligand lowest magnetic field magnetic ion matrix elements measured microwave molecular orbital neighbouring observed obtained octahedral octahedral symmetry octahedron off-diagonal operator Orbach process paramagnetic ion Paramagnetic Resonance parameters perturbation phonon Proc quantum number Section signal sin2 Soviet Phys spectra spectrum spin Hamiltonian spin-lattice relaxation spin-orbit coupling Table temperature tetragonal theory Ti3+ tonian transitions trigonal triplet unpaired electrons usually values vectors wavefunctions zero zero-field splitting