Exchange studies of the uranium-tributyl phosphate reaction
Bernard Keisch, U. S. Atomic Energy Commission. Idaho Operations Office, Phillips Petroleum Co. Atomic Energy Division
U.S. Atomic Energy Commission, Idaho Operations Office, 1959 - Reaction mechanisms (Chemistry) - 24 pages
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2TBP ANNULAR INTERFACE aqueous phase Atomic Energy Commission Bernard Keisch cent TBP chemical reaction counts/min DEPENDENCE ON TBP DEPENDENCE ON URANYL equation equilibrium constants EXCHANGE RATE EXCHANGE STUDIES fast equilibrium fit the rate follow this rate fraction collected boiled Fraction Exchanged half-time heterogeneous exchange reaction higher temperatures Idaho infinite-time interfacial resistance log Rate versus MEASURE THE EXCHANGE mechanism mono-nitrate complex nitrate dependence NITRATE ION CONCENTRATIONS nitric acid organic phase over-all rate law PHASE 1.2 ml plot of log predominant rate laws rate constant RATE DEPENDENCE RATE DETERMINATIONS rate law appears rate measurements rate of extraction rate of transfer RATE OF URANIUM rate on TBP Rate versus log reaction path reagents slow step STAINLESS STEEL straight line TBP concentration TBP molecule TBP solution TBP)org tracer was added transfer of uranium tributyl phosphate uranium transfer Uranium-233 tracer URANIUM-TRIBUTYL PHOSPHATE REACTION uranyl nitrate hexahydrate value for k-jK-^K vessel of special zero-time