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The Theories of Chemical Kinetics and Energy
Unimolecular Decompositions and Bimolecular Com
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acetone activated complex activation energy addition alkanes alkyl Amer Arrhenius Arrhenius equation assumed assumption Bodenstein bond dissociation energy bromine calculated carbon chain chem chemical chlorine combination compounds concentration corresponding curve decompose decomposition determined diethyl dissociation energy elementary reactions entropy equation equilibrium error ethane ethylene experimental results experiments Faraday Soc Figure first-order formed free radicals frequency gas reactions gases halide halogen heats of formation Hence Hinshelwood hydrogen atoms hydrogen iodide ibid investigated iodine kcal ketone kinetics Kistiakowsky measured mechanism mercury metathetical reactions method methyl radicals mole-l c.c. sec-l molecular nitric oxide nitrogen normal molecules obtained olefin oxygen photolysis Phys potential energy pressure Proc propylene quantities quenching rate constant rate factors rate of formation rate of reaction react reactants reaction of methyl reaction system reaction vessel rotational sodium atoms Steacie Szwarc Table temperature thermal tion toluene transition state theory Trotman-Dickenson unimolecular reactions values vibrational