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Some Basic Concepts
What Structures are Possible? I Predictions on the Basis
8 other sections not shown
anion arrangement atomic orbitals axis band basic bond type calculations cation CdCl2 Cdl2 chains Chapter Clarendon Press close-packed complex composition compounds configuration considered coordination number covalent bonding Crystal Chemistry crystal structure CsCl structure cubic defects described diamond directional bonding distances distorted electron configuration electronegativity electrostatic elements entropy example experimental fluorite formation H bond halides hexagonal hybrids hydrogen interaction internuclear interstitial iodine ionic radii ions Kitaigorodskii lattice energy layer structure ligands metal atoms molecular crystals molecules NaCl nearest neighbours NiAs octahedral octahedral coordination octahedral sites orbitals overlap oxides oxygen packing planar plane pseudopotential radius ratios ReO3 rf-electrons rock salt rutile shown in Figure shows silicates solids space spheres spinel stability stacking stoichiometric Structural Inorganic Chemistry structure adopted structure type symmetry Table temperature tetragonal tetrahedral tetrahedral coordination tetrahedral sites theory tion transition metals unit cell vacancies vertices Waals whilst wurtzite zinc blende