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Extent of HAtom Abstraction from the Reaction of the OH Radical with 1Butene
Kinetics of Reversible Recombination of Aromatic CCentered Radicals
The Pyrolysis of Dimethyl Sulfide Kinetics and Mechanism
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1-butene 1985 John Wiley absorption abstraction acid activation energy addition analysis Atkinson atoms autocatalysis benzaldehyde benzyl bond calculated carbocation carbon Chem Chemical Kinetics Chemistry chlorine complex concentration cresol CSTR curve cycloalkenes decay decomposition determined dimer dimethyl oxalate disilane effect equation error estimated experimental experiments factor ﬁrst ﬁrst-order ﬂow formaldehyde formation free radical gas phase hydrogen increase initial intermediate J. N. Pitts Journal of Chemical kcal kcal/mol laser measured mechanism methane methyl mixture molecule observed obtained OH radicals OH(v oxidation oxygen p-cresol peroxide photolysis Phys plot present pressure pyrolysis rate coefficient rate constants ratio reac react reactants reaction rate reactor sensitivity shown in Figure signiﬁcant silane silylene solvent species steric steric effects studies Table temperature range tert-butyl thermal thiophene tion toluene torr values wall Wiley & Sons yields