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LATTICE ENERGY OF IONIC CRYSTALS
THE SHAPE OF IONIC CRYSTALS
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alkali metal anion array atoms bonding cadmium cadmium iodide caesium chloride calculated cation and anion cation vacancy cent Chapter charge Chem chemical Chemistry concentration conduction band configuration considered coordination number covalent crystal structure crystalline cubic deviations from stoichiometry dielectric divalent effects electrons energy of formation entropy equation equilibrium example fluorite fluorite structure formula Frenkel defects increase indicates interaction intermediate phases internuclear distance interstitial ions inverse iodide ionic crystals ionization potential ions kcal/mole lattice defects lattice energy lattice sites layer Madelung constant magnetic NaCl neutron diffraction nonstoichiometric compounds nonstoichiometric phase normal lattice number of defects occupied octahedral octahedral sites ordered oxide ions oxygen Phys polarizability polarization pressure radii radius ratio random range of composition repulsion Schottky defects semiconductors sodium chloride spinel spinel structure stoichiometric stoichiometric crystal sublattice sulphide superlattice symmetry Table techniques tetrahedral tetrahedral sites thermodynamic tion titanium transition elements unit cell valency values X-ray zinc blende