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CO Oxidation over Platinum
Summary and Conclusions
Adiabatic Temperature Rise
B Kinetic Expressions
activation energy active sites adiabatic temperature rise adsorbed oxygen automotive behaviour calculated carbon deposition carbon monoxide catalyst surface catalytic converter CO2 production components compressed oxygen concentration step conversion decreases deﬁned desorb diesel oxidation catalyst diﬀerent diﬀusion dimensionless Eley-Rideal emissions Equation Euro II exothermic ﬁrst ﬂow rate free sites global hydrogen oxidation hydrogen promotion ignition increases inﬂuence inlet gas Journal of Catalysis kinetics kJ mol-1 LabVIEW light-oﬀ and light-out light-oﬀ curve light-oﬀ experiment light-oﬀ temperature literature mechanism modiﬁed mol s cm-1 monolith oxygen adsorption oxygen covered surface oxygen model parameters performed platinum platinum loading factor ppm CO ppm H2 pre-exponential factor predicted present promotion eﬀect Pt surface react reactor rest N2 selectivity shown in Figure signiﬁcant simulation space velocity species speciﬁc steady-state sticking coeﬃcient stoichiometry studies submechanism surface coverage surface reaction Surface Science surface sites Table thermocouple Topics in Catalysis typically Voltz washcoat