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acetonitrile anion band behaviour Borjesson Brillouin scattering C.A. Vincent cations charge carriers Chem concentration range conductivity drop contact ion pairs decrease dielectric constant dissociated ions dissolved dopant salt entropy experimental free ions frequency shifts glass transition temperature high frequency higher host polymer increasing salt concentration increasing temperature intensity intrachain investigated ion association ion pairs ion-ion interactions ionic conductivity ionic mobility J.R. MacCallum J.R. Stevens Kakihana L.M. Torell light scattering liquid low concentrations low salt concentrations M.A. Ratner measurements molar conductivity molecular weight monomer NaCF3SO3 number of dissociated number of free observed peak Phys polyethers polymer chains polymer electrolytes polymer-salt complexes PPG-NaCF3SO3 present study Raman scattering Raman spectra Raman Spectroscopy ratio samples Sandahl Schantz Solid State Ionics solutions solvated solvent separated Spectroscopy spectrum spin-lattice relaxation structural relaxation symmetric stretching mode temperature dependence transient cross-linking uncomplexed PPG values vibrational modes viscosity