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The NMR Spectrum
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absorption amino acids anisotropy application aqueous atoms bilayer binding Biochem biological biological membranes bonding broadening cavity cell centre chain Chapter chemical shift coils complex concentration copper crystal cytochrome oxidase detection diamagnetic effect electron spin electron transfer ENDOR energy levels enzyme ESR signal ESR spectrum ESR studies flavin free radical frequency g-value gauss haem higher than CH histidine hydrogen hyperfine splitting hyperfine structure immobilized interaction irradiation klystron laccase ligand lines lineshape linewidth lipid magnetic field magnetic resonance measured membranes method microwave power mitochondria modulation molecule motion myoglobin nitrogen nitroxide normal nuclei observed obtained orbital orientation oxidation oxygen paramagnetic paramagnetic ion peaks phase phospholipid probe protein proton pulse radiofrequency reaction redox reduced Reproduced by permission sample shown in Figure solution species spectra spectrometer spectroscopy spin label spin-lattice relaxation spin-spin substrate technique temperature transition transition-metal ions unpaired electron xanthine oxidase