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Basic Magnetic Resonance Theory
Nuclear Magnetic Resonance
4 other sections not shown
analysis angular momentum assume atom atomic orbitals benzene Bloch equations broadening calculations chemical shifts chemical-shift coil complete components coordinates cos2 coupling constant crystal field defined degeneracy determined diamagnetic difference discussed distribution electron density energy levels experimental factor field strength frequency g tensor given H1 field Hamiltonian high-resolution hyperfine induced inequivalent inhomogeneity integral interaction involved Larmor frequency ligand line-shape function linear magnetic field magnetic resonance spectroscopy magnitude matrix elements method microwave modulation molecular molecular orbitals molecular-orbital molecules Nuclear Magnetic Resonance nuclei observed obtain operator orbitals orientation oscillating paramagnetic parameters peak perturbation precess protons pulse quantum number quantum-mechanical radicals readily relaxation resonance absorption result rotating sample shown in Fig side band sin2 solution spectra spectrometer spectrum spin Hamiltonian spin system spin-lattice relaxation spin-spin spin-spin relaxation splitting structure susceptibility symmetric techniques temperature tion transitions vector wave function write