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Wave Mechanics Quantum Mechanics
Atoms with Several Electrons Vector Model
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A-type A-type doubling absorption bands absorption spectrum according angular momentum antibonding electrons antisymmetric approximation atomic orbitals band system breaking-off broken lines calculated Chapter collisions components continuum corresponding Coupling constant determined diatomic molecules dipole discussion dissociation limit doublet eigenfunctions electron configurations emission energy level diagram equation example excited field formula Franck-Condon principle frequency function Gaydon gives given ground harmonic oscillator Herzberg Hund's hyperfine structure infrared intensity distribution interaction internuclear axis internuclear distance intersection ionic isotope lower lowest magnetic magnitude maximum molecular Mulliken multiplet normal atoms nuclear spin nuclei observed obtained occur orbital oscillator perturbations Physic position potential curve potential energy predissociation Q branch quantum number repr result rotational constants rotational levels Rydberg series selection rule separated atoms similar spectrogram splitting structure symmetric TABLE 39 temperature term tion triplet upper values vibrational levels wave lengths wave mechanics wave numbers zero