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model has been found to be very useful to extract essential features
Electrical Potential Around the Macroion
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absence acid activity coefficient added additivity law alkali applied approximation assumed average becomes binding bound counter ions calculated Chapter charge density charged groups chemical potential concentration of counter concentration of macroions condition conformation consider constant contribution corresponds coulomb critical value decreases degree of dissociation degree of neutralization denotes derived determined difference dilution distance distribution effect electric equal equation equilibrium example expected experimental expressed extensive force field fluctuation free counter ions free energy free volume function given gives increase independent interaction larger length limit localized method mobile molecules monomers number of charged obtained osmotic pressure polyacrylic acid polyelectrolytes polyvalent presence properties proportional quantity radius random coil range ratio region relation repulsion respect result rods salt concentration shown in Fig shows simple salt smaller solution solvent sufficiently takes term uniform unity valence various