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StepGrowth Polymerization Polycondensation
Free Radical Chain Polymerization
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acetate acid acrylate active sites alkyl anionic polymerizations average molecular weight base molecules block copolymers butadiene calculate carbanionic catalyst cationic cellulose chain end chapter chemical compound conversion copolymerization crosslinking crystalline cyclization degree of polymerization diads diffusion double bonds electron electrophilic emulsion polymerization equation equilibrium ethylene example formation fraction free radical polymerization functions given glass transition graft graft copolymers initiator involving isobutene isotactic kinetic macromolecules methacrylate methyl molar molecular weight distribution monomer monomer concentration monomer mixture monomer molecule monomer units nucleophilic number average degree obtained occurs oxide phase polycondensation polydispersity polymer polymer chain polymer formed polymer molecules polymer particles polyvinyl primary radicals probability Problem propagation proton rate constant rate of polymerization react reactivity ratios reactor reagent ring opening polymerization soluble solvent species stoichiometric styrene substituent syndiotactic synthesis temperature termination tion transfer agent transfer reactions transition metal triad vinyl chloride viscosity yield Ziegler-Natta