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Coulomb interactions in the problem
The isomers of cyclohexane
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according angle of rotation assume atomic orbitals bewegeiyke boat configuration bond dipole C-H bond C~H+ cal/mol calculated value carbon carbon orbitals chapter charge clouds charge distributions chemical CHp-groups consider contribution coordinates corresponding coulomb interaction Coulson covalent bond cyclic molecules cyclo cyclohexane cyclohexanedione cylindrical symmetry Debye deduced dezelfde dioxane dipole moments dipoolmoment electrons energy difference entropy equal equations Eyring formula free energy gaseous give groups hexane higher hindering the free hydrogen atoms indicated interaction energy internal motion ionic Lassettre and Dean method methyl methylgroups molecular moleculen movable form movable isomer Neopentane nuclei occur octupole order of magnitude ordinary temperatures overlap charges paraffins partition function permutations Pitzer point charges potential barrier potential energy procedure repulsion RESTRICTED FREE ROTATION rigid form rigid isomer ring rotation about single single bonds specific heat stable staggered configuration stretched configuration symmetry number term tion twofold axis vectors vibration vrye wave function yt orbitals