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Chapter Two Atomic Spectra and Atomic Structure
Chapter Three Rotational Spectra
Chapter Four VibrationRotation Spectra of Diatomic Molecules
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absorption bands absorption spectrum amplitude angle angular momentum antibonding approximately atomic orbitals axes band system bond length calculated chemical shifts classical components configuration corresponding coupling constants determined diatomic molecules dipole dissociation doubly degenerate eigenfunctions electric dipole electronic transition emission energy levels equation equilibrium excited force constants force field Franck-Condon principle function fundamental bands gives ground Hamiltonian harmonic infra-red and Raman infra-red spectrum intensity interaction internuclear distance involving ionization potential isotopic linear molecules lines lowest magnetic field microwave molecular axis molecular orbitals motion non-bonding normal co-ordinates normal modes nuclei observed operator planar plane point group polarizability polyatomic molecules potential curves protons Q branch quantum mechanics quantum number Raman bands Raman spectrum resonance rotational structure Rydberg selection rules shows singlet space spectroscopy spin-orbit coupling splitting symmetric top symmetry species Table term values theory triplet ultraviolet usually valence vector vibration frequencies vibrational energy vibrational levels wavefunctions wavelengths