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B Vibrational Overtone Spectroscopy
Overview of Thesis
15 other sections not shown
acetone activated complex argon B.D. Cannon CH stretching chamber Chem chemiluminescence clusters combination band configuration delay scans diluent gas distribution of energy dye laser electrometer energized molecules expansion conditions extent of cooling F.F. Crim fast ionization gauge Fermi resonance Figure flow axis following excitation free jet conditions free jet expansion free jet spectra frequency gas pulse glass helium hot band Kalrez kcal/mole laser induced fluorescence lineshape linewidth Mach number modes mounting ring mTorr nozzle nozzle diameter observation region overtone and combination overtone transition photocathode photomultiplier photon Phys pulsed valve pumping rate constant reacting molecules reaction coordinate room temperature RRKM calculation RRKM theory sample thermostat sealing seed ratio shown in Fig stagnation pressure teflon temperature and free temporal evolution tetramethyldioxetane thermal distribution thermal energy distribution Thesis threshold energy Torr of helium total non-fixed energy triplet tube unimo vacuum vibrational overtone excitation wavelength width