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List of Tables
List of Abbreviations
Introduction to Mononuclear NonHeme Iron Enzymes and Xray
4 other sections not shown
3d orbitals 4p mixing Acta activated BLM atom average Biochemistry Bleomycin bond angle bond distances bond lengths Chem contributions coordination number crystallographic crystallographic values Debye-Waller factors determined dioxygen dioxygenases distances and angles electron energy feature energy splitting enzymes EXAFS analysis EXAFS data EXAFS signal experimental data Fe K-Edge Spectra Fe K-edge XAS Fe-N Fe-N-O angle Fe-N-O unit Fe-O Fe(II)BLM Fe(II)PAHR Fe(II)PCD Fe(II)PMA Fe(imidazole)6]Cl2 Fe(OH2)EDTA Fe(salen)NO FeEDTA-NO FePCD-NO ferric first-shell five-coordinate geometry glycerol GNXAS GNXAS Fit high spin ferrous histidine Hodgson Inorg inset intense pre-edge feature iron active Is—>3d pre-edge feature Is—>3d pre-edge region ligation lipoxygenases low spin lower energy multiple-scattering Na[Fe(OH2)EDTA nitrogen non-heme iron enzymes obtained octahedral oxidation oxygen parameters photoelectron Phys pre-edge feature pre-edge intensity protein pterin quadrupole quadrupole intensity samples shell shown in Figure solution spectrum spin ferrous complexes square pyramidal structure substrate Synchrotron Radiation Table transition two-atom variance X-ray absorption XAS Pre-Edge XAS spectra