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Chapter 2 Proton transfer to and from carbon
Chapter 3 Proton transfer to and from atoms other than carbon
A. J. Kresge A2 mechanism acetate acid and base acid catalyzed hydrolysis amines anion aqueous solution aromatic atom base catalysis Bronsted exponent Bronsted plot buffer calculated carbanion carbon acids carbonium ion carboxylic acids catalysis Chem concentration cyanocarbon decarboxylation detritiation diazoacetate ion diffusion Dioxane-water equation equilibrium constant example experimental F. A. Long Faraday Soc fast fluorene formation free energy H3O+ hydration hydrogen bond hydrolysis hydronium ion hydroxide ion intermediate involves ionization isotope exchange ketals ketones kinetic loglo measured methanol molecule nitroparaffins nucleophilic obtained occurs oxygen phenol phenylacetylene Phys pK values primary isotope effect proton transfer proton transfer reactions proton transfer step R. P. Bell rate coefficient rate-determining proton transfer rate-determining step rates of proton reactants Sect similar solvent isotope effect studied substituted substrate Table thermodynamically favourable transition