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acid adsorbed adsorption alteration aluminum amorphous amount analysis argillic associated attapulgite authigenic bentonite biotite boehmite Boom clay calcite case-hardened cations characterized chemical chlorite Clay mineral assemblages Clay Mineralogy complexes composition concentration containing copper corrensite crust crystalline crystallized dehydration Department of Agronomy Department of Geology deposits depth detrital diagenesis diagenetic diaspore environment Fe(III feldspar ferrihydrite formation formed fraction Geological geothermal glycerol glycerol solvation goethite goyazite halloysite Hawaii Institute hydrate hydrothermal hydroxy illite illite layers illite/smectite indicate Institute of Geophysics intercalated interlayer interstratified ions iron oxide jarosite kaolin kaolinite ligands material metal metamorphism mica mixed-layer molecules montmorillonite morphology numbers occur olivine oxygen isotopic particle phase potassium precipitation present pyrite quartz range reaction rectorite rocks samples sandstone saprolite sedimentary sediments shale silicate smectite solutions species spectroscopy structure sulfate surface synthetic techniques temperature thermal tuff underclays University vermiculites weathering X-ray diffraction X—ray zeolites zone