Statistical Physics |
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Page 301
... curves of intersection of the equilibrium surface with planes of constant temperature or pressure . Such curves are called equilibrium curves . Consider the points of an equilibrium curve at which the concentration of the two phases ...
... curves of intersection of the equilibrium surface with planes of constant temperature or pressure . Such curves are called equilibrium curves . Consider the points of an equilibrium curve at which the concentration of the two phases ...
Page 305
... curve near such a point is shown ; one of the straight lines of Fig . 22 coincides with the axis . P.T P.T FIG . 28 FIG . 29 FIG . 30 If one of the phases is a chemical compound of definite composition , then near a point of equal ...
... curve near such a point is shown ; one of the straight lines of Fig . 22 coincides with the axis . P.T P.T FIG . 28 FIG . 29 FIG . 30 If one of the phases is a chemical compound of definite composition , then near a point of equal ...
Page 306
... curve of the cigar is called the condensation curve and the lower one the boiling point curve . If a liquid mixture of definite composition is heated , then , at a temperature determined by the intersection of the vertical straight line ...
... curve of the cigar is called the condensation curve and the lower one the boiling point curve . If a liquid mixture of definite composition is heated , then , at a temperature determined by the intersection of the vertical straight line ...
Contents
THE BASIC PRINCIPLES OF STATISTICAL PHYSICS 1 Statistical distribution | 1 |
Statistical independence | 8 |
Liouvilles theorem | 9 |
Copyright | |
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adiabatic process angular momentum assume atoms Boltzmann Bose Bose gas Bravais lattice calculate chemical potential closed system co-ordinates coefficient components consider const constant corresponding critical point crystal degrees of freedom denote density derivative determined distribution function energy levels entropy equal equation equilibrium condition equilibrium curve expansion expression Fermi Fermi gas fluctuations formula free energy frequency gases Gibbs distribution given Hence identical integral interaction kinetic energy kT log lattice liquid macroscopic body mass matrix maximum mean value molecules momenta motion number of particles obtain P₁ partition function perfect gas phase space phonons pressure Quantum Mechanics quasi-particles radiation relation result rotational solid solution solvent specific heat spectrum spin substance Substituting subsystem symmetry T₁ thermodynamic potential thermodynamic quantities total number transition V₁ vanish vapour variables vector velocity vibrations volume ӘР эт