## High resolution nuclear magnetic resonance spectroscopy. 2 |

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Page 338

The secular determinant formed from the remaining Ay functions factorises into

four 2x2 determinants corresponding to m values of \, — J and— |; solution of the

resulting quadratic equations gives the eigenvalues and functions listed in

...

The secular determinant formed from the remaining Ay functions factorises into

four 2x2 determinants corresponding to m values of \, — J and— |; solution of the

resulting quadratic equations gives the eigenvalues and functions listed in

**Table**...

Page 369

James William Emsley, J. W. Feeney, Leslie Howard Sutcliffe. A Transitions. The

mean frequency of the two A transitions listed in

that for mx = 0 it is vA. The separation of the two A transitions is •"(/A.mA.mx) ^M/A

."!

James William Emsley, J. W. Feeney, Leslie Howard Sutcliffe. A Transitions. The

mean frequency of the two A transitions listed in

**Table**8.31 is vA + JAX mx sothat for mx = 0 it is vA. The separation of the two A transitions is •"(/A.mA.mx) ^M/A

."!

Page 384

Numerous sets of eigenvalues can be obtained by this procedure since the

of line frequencies can usually be set up in several different ways all of which

satisfy rules 1, 2, 3 and 5. To apply the rules to a measured spectrum, the first

step ...

Numerous sets of eigenvalues can be obtained by this procedure since the

**table**of line frequencies can usually be set up in several different ways all of which

satisfy rules 1, 2, 3 and 5. To apply the rules to a measured spectrum, the first

step ...

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### Contents

Introduction | 1 |

J Chem Phys 3 4 3 5 3 6 4 2 4 3 5 2 6 14 7 1 7 2 7 7 8 3 8 19 8 22 8 26 8 | 3 |

General Theory of Nuclear Magnetic Resonance | 10 |

Copyright | |

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### Common terms and phrases

AA'BB absorption bands applied atomic orbitals benzene calculated carbon Chem chemical shift chemical shift difference components compounds coupling constants cycles sec-1 diamagnetic dipole effect eigenfunctions eigenvalues electron energy levels exchange experimental fluorine given gives Gutowsky H resonance Hamiltonian hence hydrogen atoms hydrogen bonding hydrogen nuclei hydrogen resonance interaction line width linear liquid magnetic field magnetic nuclei magnetically equivalent magnitude matrix elements Mc sec-1 measured methane method methyl molecular orbital molecule multiplet non-equivalent nuclear magnetic resonance observed obtained oscillator paramagnetic parameters Phys Pople radiofrequency radiofrequency field receiver coil reference relative intensities relative signs relaxation resonance spectrum ring current rotation sample sec1 Section secular equation shielding coefficient shielding constant shown in Fig sideband signal solution solvent spectra spectrometer spin functions spin system spin-lattice relaxation substituted susceptibility symmetry Table temperature tion transition energies valence bond values vector wavefunctions zero