## High resolution nuclear magnetic resonance spectroscopy. 2 |

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Page 378

Reilly and Swalen achieved a complete ABC analysis by using a computer to

solve the matrix given in equation (8.167). They used, as trial input parameters of

the

Reilly and Swalen achieved a complete ABC analysis by using a computer to

solve the matrix given in equation (8.167). They used, as trial input parameters of

the

**matrix**,**elements**calculated from a set of ABK parameters (without iteration) ...Page 395

The appropriate symmetrised spin functions for the system and the

determinant associated with the Hamiltonian matrix factorises into two lxl, five 2x2

and one 4x4 ...

The appropriate symmetrised spin functions for the system and the

**matrix****elements**of the Hamiltonian are presented in Table 8.47. The seculardeterminant associated with the Hamiltonian matrix factorises into two lxl, five 2x2

and one 4x4 ...

Page xxxii

Analysis, energy levels 317 theoretical spectra 320 transition energies 318 AX

spin system, double resonance behaviour 247, 462 AB2 spin system 320 basic

product functions 323 diagonal

energy ...

Analysis, energy levels 317 theoretical spectra 320 transition energies 318 AX

spin system, double resonance behaviour 247, 462 AB2 spin system 320 basic

product functions 323 diagonal

**matrix elements**323 electric field effects 464energy ...

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### Contents

Introduction | 1 |

J Chem Phys 3 4 3 5 3 6 4 2 4 3 5 2 6 14 7 1 7 2 7 7 8 3 8 19 8 22 8 26 8 | 3 |

General Theory of Nuclear Magnetic Resonance | 10 |

Copyright | |

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### Common terms and phrases

AA'BB absorption bands applied atomic orbitals benzene calculated carbon Chem chemical shift chemical shift difference components compounds coupling constants cycles sec-1 diamagnetic dipole effect eigenfunctions eigenvalues electron energy levels exchange experimental fluorine given gives Gutowsky H resonance Hamiltonian hence hydrogen atoms hydrogen bonding hydrogen nuclei hydrogen resonance interaction line width linear liquid magnetic field magnetic nuclei magnetically equivalent magnitude matrix elements Mc sec-1 measured methane method methyl molecular orbital molecule multiplet non-equivalent nuclear magnetic resonance observed obtained oscillator paramagnetic parameters Phys Pople radiofrequency radiofrequency field receiver coil reference relative intensities relative signs relaxation resonance spectrum ring current rotation sample sec1 Section secular equation shielding coefficient shielding constant shown in Fig sideband signal solution solvent spectra spectrometer spin functions spin system spin-lattice relaxation substituted susceptibility symmetry Table temperature tion transition energies valence bond values vector wavefunctions zero