Experimental Electrochemistry for ChemistsIndicator electrodes; Electrochemical cells; Solvents and electrolytes; Instrumentation; Potentiometric measurements; Controlled potential methods; Controlled current methods; Electrochemical titrations. |
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Page 53
... SOLVENTS The increased use of polar aprotic solvents for electrochemical studies has inspired a search for suitable ... nonaqueous reference electrodes . Strehlow ( 79 ) also has reviewed the problem of measuring electrode potentials in ...
... SOLVENTS The increased use of polar aprotic solvents for electrochemical studies has inspired a search for suitable ... nonaqueous reference electrodes . Strehlow ( 79 ) also has reviewed the problem of measuring electrode potentials in ...
Page 315
... nonaqueous solvent systems . Although the glass electrode is universally the ... solvents almost without exception use the glass electrode in combination ... nonaqueous solvents and is an accurate representation of the changes in activity ...
... nonaqueous solvent systems . Although the glass electrode is universally the ... solvents almost without exception use the glass electrode in combination ... nonaqueous solvents and is an accurate representation of the changes in activity ...
Page 346
... nonaqueous solvents for voltammetric and polarographic measurements . A major problem is to find a system such that an adequate amount of supporting electrolyte may be introduced and dissociated to prevent migra- tion currents . For ...
... nonaqueous solvents for voltammetric and polarographic measurements . A major problem is to find a system such that an adequate amount of supporting electrolyte may be introduced and dissociated to prevent migra- tion currents . For ...
Contents
Introduction | 1 |
Indicator Electrodes | 11 |
Reference Electrodes | 34 |
Copyright | |
14 other sections not shown
Common terms and phrases
acetonitrile acid Anal anion anodic application aprotic solvents buffer calomel carbon cathodic cations cell Chem chemical chloride circuit coefficient concentration controlled potential coulometric coulometric titrations counter electrode cyclic voltammetry diffusion dimethylformamide dimethylsulfoxide dropping mercury electrode E₁ EDTA electroactive species electrochemical electrochemical cell electrochemistry electrode reaction electrode surface electrode system electrolyte electron transfer endpoint Equation equivalence point EtOH F EDTA F H2SO4 F HCI F HCl F KCI F KCl F KNO3 F NaOH F NH3 F NH4Cl feedback flow frequency frit gelatin hydrogen ion indicator electrode input instrumentation junction potential kinetic membrane method noise nonaqueous solvents operational amplifiers organic solvents output oxidation oxygen platinum electrode polarized polarography potentiometric potentiostat propylene carbonate R₁ redox reduction reference electrode resistance resistor response salt bridge shown in Figure signal silver silver-silver soluble solvation supporting electrolyte Table techniques Teflon temperature titration tube voltage voltammetry wire