Internal Rotation in Glyoxal and Collision Dynamics in Large Polyatomic Molecules |
Contents
Introduction | 2 |
Experimental | 5 |
The Torsional Potential Energy Surface | 15 |
Copyright | |
8 other sections not shown
Common terms and phrases
100 cm flight 44 transition absorption accelerating grid angle assigned azulene C.S. Parmenter calculations capillary array carrier gas Chem cis-glyoxal cm flight tube cm-¹ cm¯¹ cm¹ cm³¹ collision energy collision partner collisional complete spectra D.J. Krajnovich diatomic Dispersed Fluorescence Intensity dispersed fluorescence spectra Durig dye laser electronic energy transfer Erot excitation spectra expected positions experimental experiments final velocity fluorescence band Fluorescence Intensity Figure fluorescence spectra obtained Frequency cm glyoxal ground grid IBM-PC Inelastic Scattering initial interaction region internal rotation ionization J.R. Barker K.W. Butz laser pumping molecular beam molecule monochromator resolution naphthalene nozzle number density observed parameters photomultiplier Phys polyatomic potential energy surface quantum number rotational constants rotational contour rotational temperature S₁ S₂ signal signal-to-noise single-beam skimmer spectroscopy spectrum of figure stagnation pressure torsional energy TPES trans levels translational temperature V₁ V₂ velocity distribution velocity spread vibrational energy vibrational level vibronically induced voltage wavelength