Electron Paramagnetic ResonanceStanley Geschwind |
Contents
JahnTeller Effects in Electron Paramagnetic Resonance | 1 |
Theory of JahnTeller Effects in the EPR Spectrum of | 16 |
Theory of JahnTeller Effects in the EPR Spectrum of an Orbital | 69 |
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anisotropic axis bottleneck broadening calculated cm-¹ components corresponding covalency Cr³ cross-relaxation crystal field defect degeneracy dependence dipolar direct process discussed distorted configurations doublet dynamic Jahn-Teller effect eigenstates electron spin energy EPR spectrum excited experimental F-center factor fluorine frequency g-factor g₁ ground ground-state Hamiltonian hyperfine coupling hyperfine interaction ions isotropic Jahn-Teller coupling Jahn-Teller effect lattice levels ligand linewidth magnetic field matrix elements measured microwave Mn2+ modulation nuclear nuclei observed obtained Orbach overlap pair paramagnetic parameters perturbation phonon Phys polarization Proc proton pulse Raman relaxation process relaxation rate resonance S₁ saturation Section shown in Fig spectra spin echo spin Hamiltonian spin memory spin packet spin system spin-lattice relaxation spin-orbit spin-orbit interaction splitting static Jahn-Teller effect strain T₁ temperature tensor thermal tion transfer transition triplet two-phonon unpaired vibrational vibronic w₁ wave function Zeeman Zeeman splitting