Rotational Spectra and Molecular Structure: Physical Chemistry: A Series of Monographs

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Academic Press, Oct 27, 2016 - Science - 484 pages
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Physical Chemistry, A Series of Monographs: Rotational Spectra and Molecular Structure covers the energy levels and rotational transitions. This book is divided into nine chapters that evaluate the rigid asymmetric top molecules and the nuclear spin statistics for asymmetric tops.
Some of the topics covered in the book are the asymmetric rotor functions; rotational transition intensities; classes of molecules; nuclear spin statistics for linear molecules and symmetric tops; and classical appearance of centrifugal and coriolis forces. Other chapters deal with the energy levels and effects of centrifugal distortion, as well as the internuclear distance and moments of inertia. The discussion then shifts to the coriolis coupling effects on rotational constants and the perturbation treatment of vibration-rotational Hamiltonian. The last chapter is devoted to the examination of origin of the quadrupole interaction.
The book can provide useful information to chemists, physicists, electrical engineers, students, and researchers.
 

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Contents

Chapter 1 Rotational Spectra
1
Chapter 2 Rigid Rotor
7
Chapter 3 Centrifugal Distortion Coriolis Coupling and Fermi Resonance
51
Chapter 4 Molecular Structure
88
Chapter 5 Nuclear Quadrupole Coupling
114
Chapter 6 Internal Rotation
145
Chapter 7 Inversion
203
Chapter 8 Stark Effect
244
Derivation of the Inertial Defect
406
Coupling of Angular Momentum Vectors
409
The Van Vleck Transformation
411
Internal Rotation Splittings for the IAM
414
Barriers to Internal Rotation Determined by Microwave Spectroscopy
416
Vanishing of OddOrder Nondegenerate Stark Corrections
422
Mathieus Equation
423
Perturbation Coefficients for the Internal Rotation Problem
427

Chapter 9 Instrumentation
282
References
318
Short Table of Physical Constants Conversion Factors and Waveguide Nomenclature
392
Evaluation of Ek
393
Derivation of the Hamiltonian for Treating the VibrationRotation Interaction Problem
399
Molecular Zeeman Effect
440
Stark Corrections for a Linear Molecule
447
AUTHOR INDEX
449
SUBJECT INDEX
464
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