The Chemistry of Nonaqueous Solvents V4: Solution Phenomena and Aprotic Solvents, Volumes 1-4; Volume 5, Parts 1-2J J Lagowski The Chemistry of Nonaqueous Solvents, Volume IV: Solution Phenomena and Aprotic Solvents focuses on the chemistry of nonaqueous solvents, with emphasis on solution phenomena and aprotic solvents such as tetramethylurea, inorganic acid chlorides, cyclic carbonates, and sulfolane. This book is organized into seven chapters and begins with an overview of the theory of electrical conductivity and elementary experimental considerations, along with some of the interesting research on nonaqueous solvents. It then turns to a discussion on hydrogen bonding phenomena in nonaqueous systems as probed by four spectroscopic techniques; the different methods used in studying redox systems in nonaqueous solvents such as potentiometry and steady state diffusion methods; and the use of tetramethylurea as a nonaqueous medium for chemical reactions and chemical investigations. The reader is also introduced to inorganic acid chlorides of high dielectric constant, with special reference to antimony trichloride, and preparation methods for cyclic carbonates including vinylene carbonate, ethylene carbonate, propylene carbonate, and butylene carbonate. The book concludes with a chapter on sulfolane, focusing on its preparation and purification, physical properties, and toxicology. This book will be of interest to chemists who want to know more about nonaqueous solvents. |
Contents
Raman Spectroscopy | 48 |
Nuclear Magnetic Resonance Spectroscopy | 58 |
Ultraviolet Spectroscopy | 67 |
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1:1 electrolyte Abstr acceptor acetonitrile acid Acta alcohols alkali metal Amer amines ammonia anion antimony trichloride aprotic solvents aromatic associated band base basicity Bellamy benzophenone calculated cation Chem chemical shift Chim chloride chloroform cm¯¹ coefficients complex compounds concentration conductance cryoscopic constant cryoscopy density determined dielectric constant dilute dimer dioxane dissociation constants DMSO Electrochem electrode electrolyte enthalpy equation equilibrium constants Faraday Soc H₂O halides hydrocarbons hydrogen bonding infrared interaction ion-pairs ionic ionization Khim LiClO4 linear liquid measured methanol methods mixtures molar mole molecular molecules monomer N-H stretching nonaqueous solvents obtained oxidation perchlorate phenol Phys polarography polymers potential PROPYLENE CARBONATE proton proton donor pyridine R. M. Fuoss Raman redox reactions resonance salts SbCl SbCl3 scales soluble solutions solvation species Spectrochim spectroscopy spectrum stretching frequency stretching mode sulfolane Table temperature tetramethylurea titration values viscosity