## The Calculation of Heat Capacities of Reacting Mixtures |

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A.Jog activity coefficient actual conditions capacity at constant chemical equilibrium Comparing elements constant composition constant pres constant pressure constant volume cross terms Define the activity definition Differentiating at constant Epstein equation gives heat capacity heat content heat of reac heat of reaction Hence i8 of order interaction term internal energy International critical tables jth component log f log Kc log tr matrix form matrix notation mol fraction mol numbers change molar heat Nitric Oxide obtain order lxq order lxq.qxq.qxl order qxl order qxn.nxn.nxq percentage effect Prom REACTING MIXTURES reaction at constant reaction of second row matrix RT log scalar second reaction shown Appendix specific heat square ST 2 ST Substitution term contains Thermodynamics thesis tion at constant total heat University of Wisconsin various reactions