Physical Methods of Chemistry, Electrochemical MethodsBryant W. Rossiter, John F. Hamilton Each volume of this series heralds profound changes in both the perception and practice of chemistry. This edition presents the state of the art of all important methods of instrumental chemical analysis, measurement and control. Contributions offer introductions together with sufficient detail to give a clear understanding of basic theory and apparatus involved and an appreciation of the value, potential and limitations of the respective techniques. The emphasis of the subjects treated is on method rather than results, thus aiding the investigator in applying the techniques successfully in the laboratory. |
Contents
Choosing and Performing an Electrochemical | 1 |
OxidationReduction | 53 |
Voltammetry With Stationary and Rotated Electrodes | 191 |
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A. J. Bard absorbance acetonitrile acid Acta adsorption Anal analysis analytical anion anodic applied behavior boundary calculated cathodic cation cell cell potential charge transfer charge-transfer Chem chemical reaction Chemistry chronopotentiometric coefficient concentration conductance coulometric couple curve cyclic voltammetry dependence determined diffusion disk effect electrical electroactive species Electroanal electrochemical Electrochemistry electrode potential electrode process electrode reaction electrode surface electrolyte equation equilibrium experiment experimental Faraday frequency function half-reaction increases ion constituent Ion-Selective Electrodes ionic irreversible J. M. Savéant kinetic layer linear measurements mechanism Meites membrane metal method Nernst equation nonaqueous obtained optical oxidation parameter peak current Phys platinum plot polarography potential step potentiometric potentiostat rate constant ratio reactant redox reduction reference electrode response reversible salt scan rate Shain shown in Figure solvent spectroelectrochemistry studied supporting electrolyte techniques temperature theoretical tion titration transference number versus SCE voltage wave