Anisotropic Reorientation of Planar Molecules Measured by Nuclear Relaxation in Scalar Coupled Spin Systems |
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3-Indandione AA'BB anisotropy of molecular auto correlation behavior benzene carbon CHCH Chem chemical shift cos² coupling constant cross correlation D₂ decoupling density matrix described determined DIEGO CALIFORNIA DIEGO ERSITY DIEGO LIBRARY DIEGO UNIVERSITY dipolar relaxation dipolar spectral densities dipole-dipole eigenstate experiment experimental Figure GPYR H data H relaxation Hamiltonian IDD and MID iji'j initial rates initial slopes interactions intermolecular LIBRARY UNIVERSITY line intensities Magn matrix elements measured molecular geometry molecular motion molecular reorientation motional anisotropy motional parameters nitrobenzene NMR relaxation nuclear spin nuclei obtained ODCB perturbations Phys planar molecules proton pulse R. L. Vold R₁ relaxation data resonance rotational diffusion constants SAN DIEGO scalar coupling Section sin²e SITY solutions spectral density ratios spectral lines spectral magnetizations spin system spin-lattice relaxation Teff tensor tion transition probability UNIV values WRFF ΣΣ